Intrinsic Carrier Concentration Calculator

Free calculate intrinsic carrier concentration (n_i) for silicon at any temperature. Get instant, accurate results with our easy-to-use calculator.

Input Parameters

Typical: 300 K (27°C) for room temperature

Results

Enter temperature to calculate

What is Intrinsic Carrier Concentration?

Intrinsic carrier concentration (n_i) is the number of free electrons and holes per unit volume in a pure, undoped semiconductor at thermal equilibrium. It represents the natural concentration of charge carriers due to thermal excitation.

In silicon, n_i is highly temperature-dependent. At room temperature (300 K), n_i ≈ 1.45 × 10¹⁰ cm⁻³. As temperature increases, more electron-hole pairs are generated, dramatically increasing n_i.

This parameter is fundamental in semiconductor device physics, determining the conductivity of intrinsic material and influencing the behavior of doped semiconductors, especially at high temperatures.

Intrinsic Carrier Concentration Formula

n_i = B × T^(3/2) × exp(-E_g / (2k_B T))

Where:

  • n_i = Intrinsic carrier concentration (cm⁻³)
  • B = Material constant ≈ 5.29 × 10¹⁹ cm⁻³·K^(-3/2) for Si
  • T = Absolute temperature (K)
  • E_g = Bandgap energy (eV), temperature-dependent
  • k_B = Boltzmann constant = 8.617 × 10⁻⁵ eV/K

Temperature-dependent bandgap:

E_g(T) = 1.166 - (4.73×10⁻⁴ × T²)/(T + 636) eV

How to Calculate

  1. 1

    Convert temperature to Kelvin

    If given in °C, add 273.15. If in °F, convert via K = (°F + 459.67) × 5/9.

  2. 2

    Calculate temperature-dependent bandgap

    Use E_g(T) = 1.166 - (4.73×10⁻⁴ × T²)/(T + 636) eV for silicon.

  3. 3

    Apply the formula

    Calculate n_i = B × T^(3/2) × exp(-E_g/(2k_B T)) with B = 5.29×10¹⁹.

Practical Examples

Example 1: Room Temperature (300 K)

Calculate n_i for silicon at 300 K (27°C).

Solution:

E_g(300) = 1.166 - (4.73×10⁻⁴ × 300²)/(300 + 636) ≈ 1.124 eV

n_i = 5.29×10¹⁹ × 300^(3/2) × exp(-1.124/(2×8.617×10⁻⁵×300))

n_i ≈ 1.45 × 10¹⁰ cm⁻³

Example 2: High Temperature (400 K)

Calculate n_i at 400 K (127°C).

Solution:

E_g(400) ≈ 1.102 eV

n_i ≈ 1.38 × 10¹² cm⁻³ (much higher!)

Note: n_i increases exponentially with temperature

Applications

Device Modeling

Understanding carrier concentrations in intrinsic regions, calculating junction properties, and modeling device behavior.

Temperature Effects

Analyzing how device characteristics change with temperature, especially leakage currents and breakdown voltages.

Material Science

Characterizing semiconductor materials, understanding intrinsic conductivity, and material quality assessment.

Education

Teaching semiconductor physics, understanding thermal generation, and learning about intrinsic semiconductors.

Frequently Asked Questions

Why is n_i temperature-dependent?

Thermal energy creates electron-hole pairs by breaking covalent bonds. Higher temperature means more thermal energy, exponentially increasing the number of generated carriers.

What is the typical value at room temperature?

For silicon at 300 K, n_i ≈ 1.45 × 10¹⁰ cm⁻³. This is relatively small compared to typical doping concentrations (10¹⁵-10²⁰ cm⁻³), so intrinsic effects are usually negligible in doped devices.

How does n_i affect device operation?

At high temperatures, n_i can become comparable to doping levels, causing devices to lose their intended characteristics. This limits maximum operating temperatures.

Is n_i the same for all semiconductors?

No! Different materials have different bandgaps and material constants. Silicon has n_i ≈ 10¹⁰ cm⁻³ at 300K, while GaAs has n_i ≈ 10⁶ cm⁻³ (much lower due to larger bandgap).

What happens when n_i exceeds doping concentration?

The material becomes "intrinsic" - the natural carrier concentration dominates over doping. This typically occurs at very high temperatures and causes device failure.

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