determine saponifiction value

Calculate Saponification Value

About Saponification Value

The saponification value (SV) is the number of milligrams of potassium hydroxide (KOH) required to saponify 1 gram of fat or oil. It's used to determine the average molecular weight of fats.

From Titration:

SV = (V_blank - V_sample) × N_KOH × 56.1 / Sample Mass

From Molecular Weight:

SV = (Number of Ester Groups × 56.1 × 1000) / MW

Average MW from SV:

MW = (Number of Ester Groups × 56.1 × 1000) / SV

Where:

  • SV = Saponification value (mg KOH/g)
  • V_blank = Blank titration volume (mL)
  • V_sample = Sample titration volume (mL)
  • N_KOH = KOH normality
  • MW = Molecular weight (g/mol)

Typical Values:

• Coconut oil: 250-260
• Palm oil: 190-210
• Soybean oil: 185-195
• Olive oil: 185-200

Applications:

• Quality control of fats/oils
• Soap manufacturing
• Biodiesel production
• Food industry analysis

Saponification value is crucial in the fats and oils industry for quality control and determining the suitability of oils for specific applications.

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