what is percent ionic character calculation explanied

Calculate Percent Ionic Character

About Percent Ionic Character

Percent ionic character describes the degree to which a chemical bond is ionic rather than covalent. It's expressed as a percentage from 0% (pure covalent) to 100% (pure ionic).

Pauling's Method:

% Ionic = 100 × (1 - e^(-0.25 × (χ_A - χ_B)²))

Hannay-Smith Method:

% Ionic = 100 × (IE - EA) / (IE + EA)

From Dipole Moment:

% Ionic = 100 × (μ_observed / μ_ionic)

Where:

  • χ_A, χ_B = Electronegativities of elements A and B
  • IE = Ionization energy
  • EA = Electron affinity
  • μ = Dipole moment

Percent ionic character helps predict bond properties, molecular behavior, and chemical reactivity.

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